Tannic Acid
Product Description
Product Detail
Product Name: |
Tannic acid |
Synonyms: |
Tannic acid, AR;Tannic acid 1401-55-4 Gallotannin;TANNIC ACID PWD;Gallotannic acid 1401-55-4 Tannic acid;Tannic acid Source: Chinese natural gall nuts;Tannic acid tested according to Ph.Eur.;Tannic acid Vetec(TM) reagent grade;Tannic Acid(Pharmaceutical/Tech/Dyes/Food Grade) |
CAS: |
1401-55-4 |
MF: |
C76H52O46 |
MW: |
1701.2 |
EINECS: |
215-753-2 |
Product Categories: |
Inhibitors;Catechins & Tannins;Plant Extract;Food additive and acidulant |
Mol File: |
1401-55-4.mol |
|
Melting point |
218 °C(lit.) |
Boiling point |
862.78°C (rough estimate) |
density |
1.2965 (rough estimate) |
FEMA |
3042 | TANNIC ACID (QUERCUS SPP.) |
refractive index |
1.7040 (estimate) |
Fp |
198°C |
storage temp. |
Storage temperature: no restrictions. |
solubility |
ethanol: soluble100mg/mL, yellow to brown |
form |
Powder/Solid |
color |
Yellow to light brown |
PH |
3.5 (100g/l, H2O, 20°C) |
Water Solubility |
250 g/L (20 ºC) |
Sensitive |
Air & Light Sensitive |
Merck |
14,9052 |
BRN |
8186396 |
Stability: |
Stable. Incompatible with metallic salts, strong oxidizing agents, iron and other heavy metals. |
InChIKey |
LRBQNJMCXXYXIU-PPKXGCFTSA-N |
EPA Substance Registry System |
Tannic acid (1401-55-4) |
Hazard Codes |
Xi,Xn |
Risk Statements |
40-62-63-68-36/37/38-52/53 |
Safety Statements |
24/25-36-26-36/37/39-22-61 |
WGK Germany |
2 |
RTECS |
WW5075000 |
Autoignition Temperature |
980 °F |
TSCA |
Yes |
HS Code |
32019090 |
Hazardous Substances Data |
1401-55-4(Hazardous Substances Data) |
Toxicity |
LD50 oral in rabbit: 5gm/kg |
Production method |
Tannin is presented
in the bark and fruit of a variety of trees (such as oak and sumac) and is
also the main component of the gall formed when the trees are also subject to
attack by insects with the content being 50-70%. Crush the gallic, remove the
dead insects and insect droppings and other impurities, put into the copper
or wood extraction tank and extract with soft water; the extract was
concentrated under reduced pressure, add a small amount of ether, apply spray
drying so that the light tannin is obtained. Medicinal tannic acid is
produced through extracting the concentrated solution with ether with the
extract being bleached by sodium bisulfite and further recovery of ether to
obtain the final medicine tannin. |
Category |
toxic substances |
Toxicity grading |
highly toxic |
Acute toxicity |
intraperitoneal-mouse LD50: 150 mg/kg; intravenous-mouse LD50: 50 mg/kg |
Flammability and hazard properties |
thermal decomposition yields acrid smoke |
Storage characteristics |
warehouse: low-temperature, dry and ventilated |
Extinguishing media |
Water, carbon dioxide, foam, powder |
Chemical Properties |
Tannic acid, C14H10O9, also known as digallic acid, tannin, and gallotannin, is a yellowish powder that decomposes at 210°C (410°F). Tannic acid is derived from nutgalls. It is soluble in water and alcohol,and is insoluble in acetone and ether. Tannic acid is used in tanning,textiles, and as an alcohol denaturant. An amorphous form of tannic acid, also known as pentadigalloylglucose, exists with the formula C76H52O46. It is a yellowish to brownish powder that is very soluble in alcohol and ether.It also decomposes between 210 and 215°C (410 and 419 °F). This form is used to clarify wine or beer, as a reagent,and as a mordant in dyeing. |
Chemical Properties |
Quebracho, an evergreen tree 15 to 18 m (49 to 59 ft) tall, grows abundantly throughout South America (Argentina, in particular). The Argentine variety is characterized by its bright-red bark, rich in tannin, used for dyeing. The part used is the bark (from either the trunk or branches). Quebracho is tonic, aromatic. |
Chemical Properties |
Tannic acid or hydrolysable gallotannin is a complex polyphenolic organic structure that yields gallic acid and either glucose or quinic acid as hydrolysis products. Tannic acid is odorless or has a faint, characteristic odor and an astringent taste. |
Uses |
Tannic Acid is a sequestrant that refers to a mixture of hydrolyzable tannins of a more complex structure than gallic acid. it is used in clarifying beer and wine. see tannins. |
Uses |
nonspecific enzyme/receptor blocker |
Uses |
Clarifying agent; pH control |
Definition |
ChEBI: A gallotannin obtained by acylation of the five hydroxy groups of D-glucose by 3,4-dihydroxy-5-[(3,4,5-trihydroxybenzoyl)oxy]benzoic acid (a gallic acid dimer). |
Definition |
tannic acid: A yellowish complexorganic compound present in certainplants. It is used in dyeing as a mordant. |
Preparation |
Tannic acid is obtained by solvent extraction from the nutgalls or the excrescences that form on the young twigs of Quercus olivier and allied species of Quercus L.; from the seed pods of Tara (Caesalpinia spinosa); or from the nutgalls of various sumac species, including Rhus semialata, R. coriaria, R. glabra and R. typhia. |
Health Hazard |
Inhalation causes irritation of nose and throat, coughing, and sneezing. Ingestion may cause gastric disturbance. Contact with eyes causes irritation. |
Fire Hazard |
Special Hazards of Combustion Products: Decomposes at 210° to carbon dioxide and pyrogallol, which can form irritating vapors. |
Safety Profile |
Poison by intravenous and intraperitoneal routes. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. |
Preparation Products |
DOWEX(R) 1X8-->Gallic acid-->3,4,5-Trimethoxybenzaldehyde-->CHILLIORANGE-->Propyl gallate-->Methyl 3,4,5-trimethoxybenzoate-->D-glucose pentakis[3,4-dihydroxy-5-[(trihydroxy-3,4,5-benzoyl)oxy]benzoate]-->synthetic tanning agent No.28-->TANNASE-->synthetic tanning agent DLT-10-->Acorn shell btown-->tannalbin-->SODIUM TANNATE-->long-acting vasopressinl-->Gallic acid trimethyl ether-->Sulfonated sodium tannin-->tremella polysaccharide |
Raw materials |
Sodium bisulfite-->Naphthalene-->formaldehyde |