Nerolin Yara Yara
Product Description
Product Detail
Product Name: |
Nerolin yara yara |
CAS: |
93-04-9 |
MF: |
C11H10O |
MW: |
158.2 |
EINECS: |
202-213-6 |
Mol File: |
93-04-9.mol |
|
Melting point |
70-73 °C(lit.) |
Boiling point |
274 °C(lit.) |
density |
1.064 g/mL at 25 °C(lit.) |
FEMA |
4704 | BETA-NAPHTHYL METHYL ETHER |
refractive index |
1.5440 (estimate) |
Fp |
272-274°C |
storage temp. |
Store below +30°C. |
solubility |
H2O: soluble (completely) |
form |
Crystalline Solid |
color |
White to yellow-brown |
Water Solubility |
INSOLUBLE |
JECFA Number |
1257 |
Merck |
14,5997 |
BRN |
1859408 |
Stability: |
Stable. Combustible. Incompatible with strong oxidizing agents. |
InChIKey |
LUZDYPLAQQGJEA-UHFFFAOYSA-N |
CAS DataBase Reference |
93-04-9(CAS DataBase Reference) |
NIST Chemistry Reference |
Naphthalene, 2-methoxy-(93-04-9) |
EPA Substance Registry System |
Naphthalene, 2-methoxy- (93-04-9) |
Safety Statements |
22-24/25 |
RIDADR |
UN 3077 9 / PGIII |
WGK Germany |
2 |
RTECS |
QJ9468750 |
TSCA |
Yes |
HS Code |
29093090 |
Toxicity |
LD50 oral in rat: > 5gm/kg |
Description |
β-Naphthyl methyl ether has an intensely sweet, floral odor suggestive of orange blossoms. It is free from naphthol by-odor. It has a sweet, strawberry taste. This may be prepared from potassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthol with dimethyl sulfate or by direct esterification with methyl alcohol. |
Chemical Properties |
β-Naphthyl methyl ether has an intensely sweet, floral odor suggestive of orange blossoms; free from naphthol by-odor. It has a sweet, strawberry taste |
Chemical Properties |
white powder |
Chemical Properties |
Methyl 2-Naphthyl Ether forms white crystals (mp 73–74°C) with an intense orange blossom odor. |
Uses |
2-Methoxynaphthalene is an Impurity of the non-steroidal anti-inflammatory Naproxen (N377525). |
Preparation |
From postassium β-naphthol and methyl chloride at 300°C; by methylation of β-naphthlol with dimethyl sulfate or by direct esterification with methyl alcohol |
Purification Methods |
Fractionally distil the ether under vacuum. Crystallise it from absolute EtOH, aqueous EtOH, *C6H6, pet ether or n-heptane, and dry it under vacuum in an Abderhalden pistol or distil it in vacuo. The picrate has m 118o (from EtOH or CHCl3). [Kikuchi et al. J Phys Chem 91 574 1987, Beilstein 6 III 2969, 6 IV 4257.] |
Raw materials |
Methanol-->Sulfuric acid-->1-Aminonaphthalene-->Aurantiol (methyl anthranilate and hydroxycitronellal schiff base) |
Preparation Products |
2-Acetyl-6-methoxynaphthalene-->DL-6-METHOXY-ALPHA-METHYL-2-NAPHTHALENEMETHANOL-->6-METHOXY-2-NAPHTHOIC ACID-->6-Methoxy-2-naphthaldehyde-->6-METHOXY-1,2,3,4-TETRAHYDRONAPHTHALENE |