Dipentene
Product Description
Product Detail
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Product Name: |
Dipentene |
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CAS: |
138-86-3 |
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MF: |
C10H16 |
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MW: |
136.23 |
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EINECS: |
205-341-0 |
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Mol File: |
138-86-3.mol |
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Melting point |
-84--104 °C |
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Boiling point |
176-177 °C(lit.) |
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density |
0.844 g/mL at 25 °C(lit.) |
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vapor density |
4.7 (vs air) |
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vapor pressure |
<3 mm Hg ( 14.4 °C) |
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refractive index |
n20/D 1.473(lit.) |
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Fp |
119 °F |
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storage temp. |
2-8°C |
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form |
Liquid |
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color |
Clear colorless to pale yellow |
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Odor |
Pleasant, pine-like; lemon-like. |
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Odor Threshold |
0.038ppm |
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explosive limit |
0.7-6.1%, 150°F |
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Water Solubility |
<1 g/100mL |
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Merck |
14,5493 |
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BRN |
3587825 |
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Stability: |
Stable. Flammable. Incompatible with strong oxidizing agents. |
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InChIKey |
AJSJXSBFZDIRIS-UHFFFAOYSA-N |
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CAS DataBase Reference |
138-86-3(CAS DataBase Reference) |
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NIST Chemistry Reference |
Limonene(138-86-3) |
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EPA Substance Registry System |
Limonene (138-86-3) |
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Hazard Codes |
Xi,N |
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Risk Statements |
10-38-43-50/53 |
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Safety Statements |
24-37-60-61 |
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RIDADR |
UN 2052 3/PG 3 |
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WGK Germany |
2 |
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RTECS |
OS8350000 |
|
F |
8-10-23 |
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Autoignition Temperature |
458 °F |
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TSCA |
Yes |
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HazardClass |
3 |
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PackingGroup |
III |
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HS Code |
29021990 |
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Hazardous Substances Data |
138-86-3(Hazardous Substances Data) |
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Toxicity |
LD50 orally in Rabbit: 5300 mg/kg |
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Chemical Properties |
colourless or light yellow liquid |
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Chemical Properties |
Dipentene has a pleasant, lemon-like odor free from camphoraceous and turpentine-like notes. Limonene is the most important and widespread terpene; it is known in the d- and l- optically active forms and in the optically inactive dl-form (known as dipentene). |
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Uses |
Dipentene is used for perfuming and to mask odor. It is a chemical constituent of citrus oil. |
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Preparation |
Dipentene may be obtained by steam distillation of citrus peels and pulp resulting from the production of juice and cold pressed oils, or from deterpenation of citrus oils; it is sometimes redistilled. |
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Aroma threshold values |
Detection: 4 to 229 ppb |
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Taste threshold values |
Taste characteristics at 30 ppm: sweet, orange, citrus and terpy. |
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General Description |
A colorless liquid with an odor of lemon. Flash point 113°F. Density about 7.2 lb /gal and insoluble in water. Hence floats on water. Vapors heavier than air. Used as a solvent for rosin, waxes, rubber; as a dispersing agent for oils, resins, paints, lacquers, varnishes, and in floor waxes and furniture polishes. |
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Air & Water Reactions |
Flammable. Insoluble in water. |
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Reactivity Profile |
Cinene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. |
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Health Hazard |
Liquid irritates eyes; prolonged contact with skin causes irritation. Ingestion causes irritation of gastrointestinal tract. |
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Fire Hazard |
Behavior in Fire: Containers may explode. |
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Chemical Reactivity |
Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent. |
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Contact allergens |
Dipentene corresponds to a racemic mixture of d-limonene and l-limonene. Dipentene can be prepared from wood turpentine or by synthesis. It is used as a solvent for waxes, rosin and gums, in printing inks, perfumes, rubber compounds, paints, enamels, and lacquers. An irritant and sensitizer, dipentene caused contact dermatitis mainly in painters, polishers, and varnishers |
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Contact allergens |
Limonene is a racemic form of dand l-limonene. d-Limonene is contained in Citrus species such as citrus, orange, mandarin, and bergamot. l-Limonene is contained in Pinus pinea. The racemic form (dand l-limonene) is also named dipentene. |
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Raw materials |
Turpentine oil-->Camphor-->ALPHA-PINENE-->FEMA 2771-->Cornmint oil-->TERPENE-->White camphor oil-->Citrus Oil |
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Preparation Products |
Iron oxide red phenolic antirust paint-->1,4-Dicyanobenzene-->Hydrogen peroxide p-menthane-->P-MENTHANE-->Terpene resin。Synthetic |