Product Description

Alpha-pinene ex eucalyptus's cas code is 80-56-8

Product Detail

alpha-Pinene Basic information


Product Name:

alpha-Pinene

Synonyms:

α-Pinene 80-56-8;(±)-pin-2-ene;,6,6-Trimethyl-bicyclo[3.1.1]hept-2-ene;2,6,6-trimethylbicyclo-(3,1,1)-2-heptene;2,6,6-Trimethylbicyclo(3.1.1)-2-hept-2-ene;2,6,6-Trimethylbicyclo(3.1.1)-2-heptene;pin-2-ene;Terpene hydrocarbon

CAS:

80-56-8

MF:

C10H16

MW:

136.23

EINECS:

201-291-9

Product Categories:

Alkenes;Cyclic;Organic Building Blocks

Mol File:

80-56-8.mol



alpha-Pinene Chemical Properties


Melting point 

-55°C

Boiling point 

155-156 °C(lit.)

density 

0.858 g/mL at 25 °C(lit.)

FEMA 

2902 | ALPHA-PINENE

refractive index 

n20/D 1.465(lit.)

Fp 

90 °F

storage temp. 

Flammables area

form 

Liquid

color 

Clear colorless

Odor Threshold

0.018ppm

Water Solubility 

insoluble

Merck 

13,7527

JECFA Number

1329

Stability:

Stable. Flammable. Incompatible with strong oxidizing agents.

CAS DataBase Reference

80-56-8(CAS DataBase Reference)

NIST Chemistry Reference

«alpha»-Pinene(80-56-8)

EPA Substance Registry System

.alpha.-Pinene (80-56-8)


alpha-Pinene Safety Information


Hazard Codes 

Xi,N,Xn,F

Risk Statements 

10-36/37/38-43-50-65-51/53-38-36/38-20

Safety Statements 

26-36/37-61-37/39-29-16-36/37/39-7/9-62

RIDADR 

UN 2368 3/PG 3

WGK Germany 

1

RTECS 

DT7000000

Autoignition Temperature

491 °F

HazardClass 

3.2

PackingGroup 

III

HS Code 

29021990

Hazardous Substances Data

80-56-8(Hazardous Substances Data)


alpha-Pinene Usage And Synthesis


Chemical Properties

liquid with a turpentine odour

Chemical Properties

α-Pinene is the most widespread pinene isomer. (+)-α-Pinene, (1R,5R)-2,6,6-trimethylbicyclo[3.3.1]hept-2-ene, occurs, for example, in oil from Pinus palustris Mill., at a concentration up to 65%; oil from Pinus pinaster Soland and American oil from Pinus caribaea contain 70% and 70–80%, respectively, of the laevorotatory isomer, (?)-α-Pinene, (1S,5S)-2,6,6-trimethylbicyclo[3.3.1]hept-2-ene.
α-Pinene undergoes many reactions, of which the following are used in the fragrance industry: upon hydrogenation, α-pinene is converted to pinane, which has become an important starting material in the industrial processes used in the fragrance and flavor industry. α-Pinene can be isomerized to β-pinene with high selectivity for β-pinene formation. Hydration with simultaneous ring opening yields terpineol and cis-terpin hydrate. Pyrolysis of α-pinene yields a mixture of ocimene and alloocimene.
Pure α-pinene is obtained by distillation of turpentine oils. As a fragrance substance, it is used to improve the odor of industrial products.However, it is farmore important as a starting material in industrial syntheses, for example, terpineols, borneol, and camphor.

Chemical Properties

α-Pinene has a characteristic odor of pine. It is turpentine-like. The oxidized material has a resin-like odor.

Uses

α-Pinene was used as standard in headspace solid-phase microextraction-gas chromatographic analysis of volatile compounds in virgin olive oils 1 . It was used in the synthesis of cesium-doped heteropolyacid having potential application in biodiesel synthesis.

Uses

α-Pinene was used as standard in headspace solid-phase microextraction-gas chromatographic analysis of volatile compounds in virgin olive oils. It was used in the synthesis of cesium-doped heteropolyacid having potential application in biodiesel synthesis

Definition

ChEBI: A pinene that is bicyclo[3.1.1]hept-2-ene substituted by methyl groups at positions 2, 6 and 6 respectively.

Production Methods

α-Pinene occurs naturally in a variety of trees and shrubs, including more than 400 essential oils, and air concentrations near pine forests may reach 500–1200 mg/m3. Total U.S. emission of α-pinene from deciduous and coniferous forests amounts to 6.6 million tons annually. An estimated emission rate of α-pinene from natural sources to the atmosphere is 1.84×10 -10 g/cm3/s.

Preparation

From turpentine, by distillation.

Aroma threshold values

Detection: 2.5 to 62 ppb. Aroma characteristics at 1.0%: terpy citrus and spicy, woody pine and turpentinelike with a slight cooling camphoraceous nutmeglike nuance, a fresh herbal lift and a tropical fruit top note.

Taste threshold values

Taste characteristics at 10 ppm: intense, woody, piney and terpy with camphoraceous and turpentine notes. It has herbal, spicy and slightly tropical mango nuances.

General Description

A clear colorless liquid with a turpentine odor. Flash point 91°F. Less dense than water and insoluble in water. Vapors are heavier than air. Used as a solvent.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

alpha-Pinene may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen.

Health Hazard

Harmful if swallowed, inhaled or absorbed through skin. High concentrations are extremely destructive to mucous membrane and upper respiratory tract, eyes and skin. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

Fire Hazard

Special Hazards of Combustion Products: Vapor may travel considerable distance to source of ignition and flashback. Container explosion may occur during fire conditions. Forms explosive mixtures in air.

Contact allergens

Alpha-pinene is the major constituent of turpentine (about 80%). It exists in levogyre form in European turpentine and in dextrogyre form in turpentine found in North-Americans. Sensitization occurs mainly in painters, polishers, and varnishers, and in those in the perfume and in the ceramics industry.

Safety Profile

A deadly poison by inhalation. Moderately toxic by ingestion. An eye, mucous membrane, and severe human skin irritant. Flammable liquid. A dangerous fire hazard when exposed to heat, flame, or oxidizing materials. To fight fire, use foam, Co2, dry chemical. Explodes on contact with nitrosyl perchlorate.


alpha-Pinene Preparation Products And Raw materials


Preparation Products

Camphene-->Dihydromyrcenol-->(1S)-(-)-alpha-Pinene

Raw materials

Turpentine oil


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